| 陈文通,胡龙.具有3维阳离子超分子框架结构的(4,4'-BipyH2)2(FeCl4)3·Cl的水热合成和晶体结构[J].井冈山大学自然版,2010,(4): |
| 具有3维阳离子超分子框架结构的(4,4'-BipyH2)2(FeCl4)3·Cl的水热合成和晶体结构 |
| HYDROTHERMAL SYNTHESIS AND CRYSTAL STRUCTURE OF (4,4'-BIPYH2)2(FECL4)3CL WITH A 3-D CATIONIC SUPRAMOLECULAR FRAMEWORK |
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| DOI： |
| 中文关键词: 联吡啶 氯化物 晶体 水热 铁 |
| 英文关键词: Bipyridine chloride crystal hydrothermal iron |
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| 摘要点击次数: 1941 |
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| 中文摘要: |
| 通过水热反应合成了一种新的具有3维阳离子超分子框架结构的化合物(4,4'-BipyH2)2(FeCl4)3·Cl(1),并对该化合物进行了X-射线单品结构表征.该化合物具有孤立结构特征,在分子中含有4,4'-BipyH2,FeCl4和氯离子.它们通过氢键形成3维阳离子超分子框架结构.(FeCl4)-离子位于该超分子框架结构的空隙中. |
| 英文摘要: |
| A new compound with a three-dimensional cationic supramolecular framework, (4,4'-BipyH2)2(FeCl4)3Cl(1),has been synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The crystal structure analysis reveals that the title compound features an isolated structure, based on 4,4'-BipyH2 moieties, Cl- anions and an iron atom terminally bound by four chlorine atoms. The 4,4'-BipyH2 moieties, Cl- anions and (FeCl4)- anions are interconnected via hydrogen bonds to form a 3-D cationic supramolecular framework with some (FeCl4)- anions residing in the voids of the cationic supramolecular framework. |
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